{"id":1911,"date":"2026-11-01T03:00:00","date_gmt":"2026-10-31T18:00:00","guid":{"rendered":"https:\/\/quantumsea.net\/?p=1911"},"modified":"2026-10-31T14:28:11","modified_gmt":"2026-10-31T05:28:11","slug":"qs-mof-magnesium-solvent-dynamics-20261029","status":"publish","type":"post","link":"https:\/\/quantumsea.net\/?p=1911","title":{"rendered":"MOF\u306e\u30de\u30b0\u30cd\u30b7\u30a6\u30e0\u30a4\u30aa\u30f3\u4f1d\u5c0e\u3001\u6eb6\u5a92\u5206\u5b50\u306e\u52d5\u304d\u304b\u3089\u4ed5\u7d44\u307f\u306b\u8feb\u308b"},"content":{"rendered":"<p>\u96fb\u6c60\u306e\u4e2d\u3067\u30a4\u30aa\u30f3\u3092\u52d5\u304d\u3084\u3059\u304f\u3059\u308b\u306b\u306f\u3001\u901a\u308a\u9053\u3060\u3051\u3067\u306a\u304f\u3001\u305d\u306e\u5468\u56f2\u306b\u3044\u308b\u5206\u5b50\u306e\u50cd\u304d\u3082\u77e5\u308b\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002\u7406\u5316\u5b66\u7814\u7a76\u6240\u3001\u6771\u4eac\u7406\u79d1\u5927\u5b66\u3001\u6771\u4eac\u5927\u5b66\u306a\u3069\u306e\u5171\u540c\u7814\u7a76\u30b0\u30eb\u30fc\u30d7\u306f\u3001\u7d30\u304b\u306a\u5b54\u3092\u6301\u3064\u6750\u6599\u306b\u53d6\u308a\u8fbc\u307e\u308c\u305f\u30a2\u30bb\u30c8\u30cb\u30c8\u30ea\u30eb\u3068\u3044\u3046\u5206\u5b50\u306e\u52d5\u304d\u3092\u8abf\u3079\u3001\u30de\u30b0\u30cd\u30b7\u30a6\u30e0\u30a4\u30aa\u30f3\u304c\u79fb\u52d5\u3057\u3084\u3059\u304f\u306a\u308b\u4ed5\u7d44\u307f\u3092\u652f\u3048\u308b\u5b9f\u9a13\u7d50\u679c\u3092\u5831\u544a\u3057\u307e\u3057\u305f\u3002<\/p>\n<p>\u8ad6\u6587\u306f2026\u5e749\u670829\u65e5\u306bJournal 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class=\"wp-block-table\">\n<table>\n<thead>\n<tr>\n<th>\u6bd4\u3079\u308b\u7d44\u307f\u5408\u308f\u305b<\/th>\n<th>\u5207\u308a\u5206\u3051\u305f\u3044\u5f71\u97ff<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u7d30\u5b54\u306e\u5916\u306eAN\u3068\u3001\u5869\u3092\u542b\u3080AN<\/td>\n<td>\u5869\u3092\u52a0\u3048\u308b\u3053\u3068\u304c\u5206\u5b50\u904b\u52d5\u306b\u4e0e\u3048\u308b\u5f71\u97ff<\/td>\n<\/tr>\n<tr>\n<td>\u7d30\u5b54\u306e\u5916\u306eAN\u3068\u3001MOF\u5185\u306eAN<\/td>\n<td>\u7d30\u5b54\u306e\u58c1\u306b\u56f2\u307e\u308c\u308b\u5f71\u97ff<\/td>\n<\/tr>\n<tr>\n<td>MOF\u5185\u306eAN\u3068\u3001MOF\u5185\u306eAN\uff0b\u5869<\/td>\n<td>\u9589\u3058\u8fbc\u3081\u3089\u308c\u305f\u74b0\u5883\u3067\u5869\u304c\u52a0\u308f\u308b\u5f71\u97ff<\/td>\n<\/tr>\n<\/tbody>\n<\/table><figcaption>\u8a66\u6599\u306e\u6bd4\u8f03\u304c\u679c\u305f\u3059\u5f79\u5272\u3092\u6574\u7406\u3057\u305f\u3082\u306e\u3002\u5b9f\u6e2c\u5024\u3092\u518d\u73fe\u3057\u305f\u8868\u3067\u306f\u3042\u308a\u307e\u305b\u3093\u3002<\/figcaption><\/figure>\n<p>\u89e3\u6790\u3067\u306f\u3001\u5869\u3092\u542b\u307e\u306a\u3044\u8a66\u6599\u306eAN\u306f\u9023\u7d9a\u7684\u306a\u62e1\u6563\u30e2\u30c7\u30eb\u3067\u8aac\u660e\u3055\u308c\u3001\u5869\u3092\u542b\u3080\u8a66\u6599\u306f\u3001\u3042\u308b\u5834\u6240\u304b\u3089\u5225\u306e\u5834\u6240\u3078\u98db\u3073\u79fb\u308b\u300c\u30b8\u30e3\u30f3\u30d7\u62e1\u6563\u300d\u306e\u30e2\u30c7\u30eb\u3067\u3088\u304f\u8aac\u660e\u3055\u308c\u307e\u3057\u305f\u3002AN-Mg-MOF\u3067\u6c42\u3081\u3089\u308c\u305fAN\u306e\u5e73\u5747\u7684\u306a\u30b8\u30e3\u30f3\u30d7\u8ddd\u96e2\u306f\u7d041.6\u30aa\u30f3\u30b0\u30b9\u30c8\u30ed\u30fc\u30e0\u3001\u30ca\u30ce\u30e1\u30fc\u30c8\u30eb\u306b\u76f4\u3059\u3068\u7d040.16\u30ca\u30ce\u30e1\u30fc\u30c8\u30eb\u3067\u3057\u305f\u3002\u3053\u308c\u306fAN\u306e\u904b\u52d5\u306b\u3064\u3044\u3066\u306e\u5024\u3067\u3042\u308a\u3001Mg<sup>2+<\/sup>\u304c\u4e00\u5ea6\u306b\u9032\u3080\u8ddd\u96e2\u3067\u306f\u3042\u308a\u307e\u305b\u3093\u3002<\/p>\n<h2>\u6eb6\u5a92\u306e\u52d5\u304d\u304c\u9045\u304f\u3066\u3082\u3001\u30a4\u30aa\u30f3\u3092\u52a9\u3051\u308b\u3053\u3068\u304c\u3042\u308b<\/h2>\n<p>AN\u306e\u62e1\u6563\u4fc2\u6570\u306f\u3001\u7d30\u5b54\u306e\u5916\u306eAN\u3001\u5869\u3092\u542b\u3080AN\u3001MOF\u5185\u306eAN\u3001MOF\u5185\u306eAN\u3068\u5869\u306e\u9806\u306b\u5c0f\u3055\u304f\u306a\u308a\u307e\u3057\u305f\u3002\u3053\u3053\u3067\u3044\u3046\u62e1\u6563\u4fc2\u6570\u306f\u3001AN\u304c\u3069\u306e\u7a0b\u5ea6\u5e83\u304c\u3063\u3066\u3044\u304f\u304b\u3092\u8868\u3059\u91cf\u3067\u3059\u3002\u6750\u6599\u5168\u4f53\u306eMg<sup>2+<\/sup>\u4f1d\u5c0e\u5ea6\u3068\u540c\u3058\u6e2c\u5b9a\u91cf\u3067\u306f\u3042\u308a\u307e\u305b\u3093\u3002<\/p>\n<p>\u3053\u306e\u9055\u3044\u3092\u62bc\u3055\u3048\u308b\u3068\u3001\u300cAN\u306e\u52d5\u304d\u304c\u9045\u3044\u306e\u306b\u3001\u306a\u305cMg<sup>2+<\/sup>\u3092\u52d5\u304d\u3084\u3059\u304f\u3059\u308b\u3068\u8003\u3048\u308b\u306e\u304b\u300d\u3068\u3044\u3046\u7591\u554f\u3092\u6574\u7406\u3067\u304d\u307e\u3059\u3002\u7814\u7a76\u30c1\u30fc\u30e0\u306f\u3001AN\u304cMg<sup>2+<\/sup>\u3068\u306e\u7d50\u3073\u3064\u304d\u3092\u4f5c\u3063\u305f\u308a\u5207\u3063\u305f\u308a\u3057\u306a\u304c\u3089\u62e1\u6563\u3057\u3066\u3044\u308b\u3068\u89e3\u91c8\u3057\u3066\u3044\u307e\u3059\u3002\u30a4\u30aa\u30f3\u306e\u305d\u3070\u306b\u3068\u3069\u307e\u308b\u3053\u3068\u306fAN\u81ea\u8eab\u306e\u81ea\u7531\u306a\u52d5\u304d\u3092\u59a8\u3052\u307e\u3059\u304c\u3001\u305d\u306e\u7d50\u3073\u3064\u304d\u304c\u5468\u56f2\u3068\u306e\u9759\u96fb\u7684\u306a\u76f8\u4e92\u4f5c\u7528\u3092\u5f31\u3081\u308b\u306a\u3089\u3001Mg<sup>2+<\/sup>\u306e\u79fb\u52d5\u306b\u306f\u6709\u5229\u306b\u50cd\u304f\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059\u3002<\/p>\n<p>\u4eca\u56de\u306e\u7d50\u679c\u306f\u3001\u3053\u306e\u8aac\u660e\u3068\u6574\u5408\u3059\u308b\u5206\u5b50\u904b\u52d5\u3092\u793a\u3057\u3066\u3044\u307e\u3059\u3002\u305f\u3060\u3057\u3001AN\u306e\u52d5\u304d\u3068Mg<sup>2+<\/sup>\u306e\u52d5\u304d\u306f\u5225\u3067\u3059\u3002AN\u306e\u30b8\u30e3\u30f3\u30d7\u8ddd\u96e2\u3084\u62e1\u6563\u4fc2\u6570\u3092\u3001\u305d\u306e\u307e\u307eMg<sup>2+<\/sup>\u306e\u79fb\u52d5\u8ddd\u96e2\u3084\u901f\u3055\u3078\u7f6e\u304d\u63db\u3048\u3066\u306f\u3044\u3051\u307e\u305b\u3093\u3002<\/p>\n<h2>\u6750\u6599\u306e\u4ed5\u7d44\u307f\u3068\u3001\u96fb\u6c60\u306e\u8a55\u4fa1\u3092\u3064\u306a\u3050\u306b\u306f<\/h2>\n<p>\u6b21\u306e\u6750\u6599\u3092\u6bd4\u8f03\u3059\u308b\u3068\u304d\u306b\u306f\u3001\u30a4\u30aa\u30f3\u4f1d\u5c0e\u5ea6\u306e\u6570\u5024\u306b\u52a0\u3048\u3066\u3001\u7d30\u5b54\u3001\u5869\u3001\u6eb6\u5a92\u5206\u5b50\u306e\u7d44\u307f\u5408\u308f\u305b\u3092\u305d\u308d\u3048\u3066\u8aad\u3080\u3053\u3068\u304c\u5927\u5207\u306b\u306a\u308a\u307e\u3059\u3002\u540c\u3058MOF\u3067\u3082\u3001\u4e2d\u306b\u4fdd\u6301\u3059\u308b\u5206\u5b50\u304c\u5909\u308f\u308c\u3070\u3001\u30a4\u30aa\u30f3\u3092\u53d6\u308a\u5dfb\u304f\u74b0\u5883\u306f\u5909\u308f\u308b\u304b\u3089\u3067\u3059\u3002<\/p>\n<p>\u4e00\u65b9\u3001\u6750\u6599\u4e2d\u3092\u30a4\u30aa\u30f3\u304c\u901a\u308a\u3084\u3059\u3044\u3053\u3068\u3060\u3051\u3067\u3001\u5145\u653e\u96fb\u3067\u304d\u308b\u96fb\u6c60\u304c\u5b8c\u6210\u3057\u305f\u3068\u306f\u3044\u3048\u307e\u305b\u3093\u3002\u96fb\u6975\u3068\u63a5\u3059\u308b\u90e8\u5206\u3067\u53cd\u5fdc\u304c\u5b89\u5b9a\u3057\u3066\u7d9a\u304f\u304b\u3001\u7e70\u308a\u8fd4\u3057\u4f7f\u3048\u308b\u304b\u3001\u3068\u3044\u3063\u305f\u8a55\u4fa1\u3078\u3064\u306a\u3050\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002Mg<sup>2+<\/sup>\u304c\u4e8c\u3064\u306e\u96fb\u8377\u3092\u6301\u3064\u3053\u3068\u3082\u3001\u96fb\u6c60\u306e\u5bb9\u91cf\u3084\u30a8\u30cd\u30eb\u30ae\u30fc\u5bc6\u5ea6\u304c\u81ea\u52d5\u7684\u306b2\u500d\u306b\u306a\u308b\u3053\u3068\u3092\u610f\u5473\u3057\u307e\u305b\u3093\u3002\u4eca\u56de\u306e\u9032\u5c55\u306f\u3001\u6027\u80fd\u5024\u306e\u80cc\u5f8c\u306b\u3042\u308b\u5206\u5b50\u306e\u5f79\u5272\u3092\u8abf\u3079\u3001\u6750\u6599\u8a2d\u8a08\u306e\u7406\u7531\u3092\u3088\u308a\u5177\u4f53\u7684\u306b\u3057\u305f\u70b9\u306b\u3042\u308a\u307e\u3059\u3002<\/p>\n<h2>\u51fa\u5178<\/h2>\n<ol>\n<li>Shun Sato et al., <a href=\"https:\/\/doi.org\/10.1021\/jacs.6c11926\">Calorimetric and Quasielastic Neutron Scattering Studies on a Mg-Ion Conductor Using a Metal\u2013Organic Framework MIL-101 Involving Acetonitrile<\/a>, Journal of the American Chemical Society 148, 43303\u201343312\uff08\u30aa\u30f3\u30e9\u30a4\u30f3\u516c\u958b2026\u5e749\u670829\u65e5\u3001\u53f7\u63b2\u8f0910\u670814\u65e5\uff09\u3002<a href=\"https:\/\/pubmed.ncbi.nlm.nih.gov\/42913559\/\">\u516c\u958b\u8981\u65e8\u3068\u66f8\u8a8c\u60c5\u5831<\/a>\u3002<\/li>\n<li>\u7406\u5316\u5b66\u7814\u7a76\u6240\u307b\u304b\u3001<a href=\"https:\/\/www.riken.jp\/press\/2026\/20261021_2\/index.html\">\u91d1\u5c5e\uff0d\u6709\u6a5f\u69cb\u9020\u4f53\u306b\u304a\u3051\u308bMg<sup>2+<\/sup>\u4f1d\u5c0e\u6a5f\u69cb\u306e\u5b9f\u9a13\u7684\u88cf\u4ed8\u3051<\/a>\uff082026\u5e7410\u670821\u65e5\uff09\u3002\u7814\u7a76\u65b9\u6cd5\u3001\u56f31\u301c3\u3068\u89e3\u8aac\u3002<a href=\"https:\/\/www.issp.u-tokyo.ac.jp\/maincontents\/news2.html?pid=32629\">\u6771\u4eac\u5927\u5b66\u7269\u6027\u7814\u7a76\u6240\u306e\u7d39\u4ecb<\/a>\uff0810\u670826\u65e5\uff09\u3082\u540c\u3058\u5171\u540c\u7814\u7a76\u306b\u95a2\u3059\u308b\u3082\u306e\u3067\u3059\u3002<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"<p>\u96fb\u6c60\u306e\u4e2d\u3067\u30a4\u30aa\u30f3\u3092\u52d5\u304d\u3084\u3059\u304f\u3059\u308b\u306b\u306f\u3001\u901a\u308a\u9053\u3060\u3051\u3067\u306a\u304f\u3001\u305d\u306e\u5468\u56f2\u306b\u3044\u308b\u5206\u5b50\u306e\u50cd\u304d\u3082\u77e5\u308b\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002\u7406\u5316\u5b66\u7814\u7a76\u6240\u3001\u6771\u4eac\u7406\u79d1\u5927\u5b66\u3001\u6771\u4eac\u5927\u5b66\u306a\u3069\u306e\u5171\u540c\u7814\u7a76\u30b0\u30eb\u30fc\u30d7\u306f\u3001\u7d30\u304b\u306a\u5b54\u3092\u6301\u3064\u6750\u6599\u306b\u53d6\u308a\u8fbc\u307e\u308c\u305f\u30a2\u30bb\u30c8\u30cb\u30c8\u30ea\u30eb\u3068\u3044\u3046\u5206\u5b50 [&hellip;]<\/p>\n","protected":false},"author":3,"featured_media":1910,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":true,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_feature_clip_id":0,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":false,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2},"jetpack_post_was_ever_published":false},"categories":[34],"tags":[370],"class_list":["post-1911","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-materials-manufacturing","tag-metal-organic-framework"],"jetpack_publicize_connections":[],"jetpack_sharing_enabled":true,"jetpack_featured_media_url":"https:\/\/quantumsea.net\/wp-content\/uploads\/2026\/10\/qs-mof-magnesium-solvent-dynamics-20261029-9f266ee02906.png","_links":{"self":[{"href":"https:\/\/quantumsea.net\/index.php?rest_route=\/wp\/v2\/posts\/1911","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/quantumsea.net\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/quantumsea.net\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/quantumsea.net\/index.php?rest_route=\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/quantumsea.net\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1911"}],"version-history":[{"count":1,"href":"https:\/\/quantumsea.net\/index.php?rest_route=\/wp\/v2\/posts\/1911\/revisions"}],"predecessor-version":[{"id":1933,"href":"https:\/\/quantumsea.net\/index.php?rest_route=\/wp\/v2\/posts\/1911\/revisions\/1933"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/quantumsea.net\/index.php?rest_route=\/wp\/v2\/media\/1910"}],"wp:attachment":[{"href":"https:\/\/quantumsea.net\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1911"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/quantumsea.net\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=1911"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/quantumsea.net\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=1911"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}