{"id":1965,"date":"2026-11-01T17:00:00","date_gmt":"2026-11-01T08:00:00","guid":{"rendered":"https:\/\/quantumsea.net\/?p=1965"},"modified":"2026-11-04T22:55:55","modified_gmt":"2026-11-04T13:55:55","slug":"qs-mof-triplet-odmr-20261031","status":"publish","type":"post","link":"https:\/\/quantumsea.net\/?p=1965","title":{"rendered":"\u6771\u5927\u30fb\u65e5\u672c\u96fb\u5b50\u3089\u3001MOF\u306e\u4e09\u91cd\u9805\u30b9\u30d4\u30f3\u3092\u8fd1\u8d64\u5916\u5149\u3067\u8aad\u307f\u51fa\u3059"},"content":{"rendered":"<p>\u5c0f\u3055\u306a\u5206\u5b50\u304c\u5165\u308c\u308b\u5b54\u3092\u6301\u3064\u6750\u6599\u304b\u3089\u3001\u96fb\u5b50\u30b9\u30d4\u30f3\u306e\u72b6\u614b\u3092\u5149\u3067\u8aad\u307f\u53d6\u308b\u3002\u305d\u306e\u4e8c\u3064\u3092\u4e00\u3064\u306e\u7d50\u6676\u3067\u4e21\u7acb\u3067\u304d\u308c\u3070\u3001\u5916\u304b\u3089\u8fd1\u3065\u304f\u5206\u5b50\u3068\u3001\u91cf\u5b50\u72b6\u614b\u306e\u5909\u5316\u3092\u6e2c\u308b\u4ed5\u7d44\u307f\u3068\u3092\u7d50\u3073\u4ed8\u3051\u3089\u308c\u307e\u3059\u3002<\/p>\n<p>\u6771\u4eac\u5927\u5b66\u3001\u65e5\u672c\u96fb\u5b50\u3001\u30b0\u30e9\u30b9\u30b4\u30fc\u5927\u5b66\u306a\u3069\u306e\u5171\u540c\u7814\u7a76\u30c1\u30fc\u30e0\u306f\u3001\u91d1\u5c5e\u2013\u6709\u6a5f\u69cb\u9020\u4f53\uff08MOF\uff09\u306e\u4e2d\u306b\u4e26\u3076\u30dd\u30eb\u30d5\u30a3\u30ea\u30f3\u5206\u5b50\u3092\u4f7f\u3044\u3001\u8fd1\u8d64\u5916\u306e\u767a\u5149\u3092\u901a\u3058\u3066\u4e09\u91cd\u9805\u30b9\u30d4\u30f3\u306e\u5171\u9cf4\u3092\u691c\u51fa\u3057\u307e\u3057\u305f\u30022026\u5e7410\u67089\u65e5\u306b\u767a\u8868\u30fb\u8ad6\u6587\u516c\u958b\u3055\u308c\u305f\u7814\u7a76\u3067\u3059\u3002\u4eca\u56de\u78ba\u304b\u3081\u305f\u306e\u306f\u3001\u5149\u3067\u30b9\u30d4\u30f3\u3092\u8aad\u307f\u51fa\u3059\u6750\u6599\u306e\u57fa\u790e\u3067\u3042\u308a\u3001\u306b\u304a\u3044\u3084\u751f\u4f53\u7269\u8cea\u3092\u6e2c\u308b\u30bb\u30f3\u30b5\u30fc\u305d\u306e\u3082\u306e\u3067\u306f\u3042\u308a\u307e\u305b\u3093\u3002<\/p>\n<section 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K\u3067\u6e2c\u308b\u3068\u3001\u5916\u90e8\u78c1\u5834\u3092\u304b\u3051\u306a\u3044\u6761\u4ef6\u3067\u7d04300\u3001770\u30011,070 MHz\u306b\u5171\u9cf4\u304c\u73fe\u308c\u3001800 nm\u3088\u308a\u9577\u3044\u6ce2\u9577\u3092\u96c6\u3081\u308b\u65b9\u304c\u3001\u77ed\u3044\u6ce2\u9577\u5074\u3088\u308a\u5f37\u3044ODMR\u4fe1\u53f7\u3092\u5f97\u3089\u308c\u307e\u3057\u305f\u3002\u3053\u308c\u3089\u306e\u5468\u6ce2\u6570\u306f\u30b9\u30d4\u30f3\u6e96\u4f4d\u9593\u306e\u5171\u9cf4\u3092\u793a\u3059\u5024\u3067\u3001\u8a08\u7b97\u3084\u6e2c\u5b9a\u3092\u6bce\u79d2\u4f55\u56de\u3067\u304d\u308b\u304b\u3092\u8868\u3059\u3082\u306e\u3067\u306f\u3042\u308a\u307e\u305b\u3093\u3002<\/p>\n<p>\u767a\u5149\u304c\u5927\u304d\u304f\u70b9\u6ec5\u3059\u308b\u5b9f\u9a13\u3067\u306f\u306a\u304f\u3001\u5149\u306e\u5f37\u3055\u306b\u542b\u307e\u308c\u308b\u3054\u304f\u5c0f\u3055\u306a\u5dee\u3092\u691c\u51fa\u3057\u3066\u3044\u307e\u3059\u3002\u307e\u305f\u3001\u5916\u90e8\u78c1\u5834\u3092\u5909\u3048\u308b\u3068\u5171\u9cf4\u306e\u4f4d\u7f6e\u3082\u5909\u308f\u308a\u307e\u3057\u305f\u3002\u5149\u3067\u898b\u3066\u3044\u308b\u4fe1\u53f7\u3068\u30b9\u30d4\u30f3\u306e\u78c1\u6c17\u7684\u306a\u5fdc\u7b54\u304c\u7d50\u3073\u4ed8\u3044\u3066\u3044\u308b\u3053\u3068\u304c\u3001\u6750\u6599\u3068\u3057\u3066\u306e\u8981\u70b9\u3067\u3059\u3002<\/p>\n<h2>\u767a\u5149\u3001\u30b9\u30d4\u30f3\u306e\u6301\u7d9a\u3001\u5149\u306b\u3088\u308b\u8aad\u307f\u51fa\u3057\u306f\u5206\u3051\u3066\u898b\u308b<\/h2>\n<p>\u3053\u306e\u7814\u7a76\u3092\u30bb\u30f3\u30b5\u30fc\u6750\u6599\u3068\u3057\u3066\u8a55\u4fa1\u3059\u308b\u3068\u304d\u306f\u3001\u4f55\u3092\u3069\u306e\u6e29\u5ea6\u3067\u78ba\u304b\u3081\u305f\u304b\u304c\u5927\u5207\u3067\u3059\u3002\u5ba4\u6e29\u3067\u5149\u304c\u51fa\u305f\u3053\u3068\u3068\u3001\u5ba4\u6e29\u3067\u30b9\u30d4\u30f3\u3092\u5149\u304b\u3089\u8aad\u307f\u51fa\u305b\u305f\u3053\u3068\u306f\u3001\u540c\u3058\u7d50\u679c\u3067\u306f\u3042\u308a\u307e\u305b\u3093\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u8abf\u3079\u305f\u6027\u8cea<\/th>\n<th>\u4eca\u56de\u306e\u6761\u4ef6\u3068\u5206\u304b\u308b\u3053\u3068<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5149\u3092\u5f53\u3066\u305f\u3042\u3068\u306e\u767a\u5149<\/td>\n<td>\u5ba4\u6e29\u306877 K\u3067\u6e2c\u5b9a\u3002\u77ed\u3044\u86cd\u5149\u3068\u3001\u9577\u304f\u7d9a\u304f\u8fd1\u8d64\u5916\u306e\u767a\u5149\u3092\u8abf\u3079\u305f\u3002<\/td>\n<\/tr>\n<tr>\n<td>\u30b9\u30d4\u30f3\u306e\u4f4d\u76f8\u304c\u305d\u308d\u3046\u6642\u9593\u3001T\u2082<\/td>\n<td>50 K\u306e\u96fb\u5b50\u5e38\u78c1\u6027\u5171\u9cf4\u6e2c\u5b9a\u3002\u52b1\u8d77\u3092\u5f31\u3081\u305f\u6761\u4ef6\u3067\u306f\u7d044.8\u30de\u30a4\u30af\u30ed\u79d2\u3002\u5149\u306e\u5f37\u3055\u306b\u3088\u3063\u3066\u5024\u304c\u5909\u308f\u308b\u3002<\/td>\n<\/tr>\n<tr>\n<td>\u767a\u5149\u306b\u3088\u308b\u30b9\u30d4\u30f3\u5171\u9cf4\u306e\u8aad\u307f\u51fa\u3057<\/td>\n<td>77 K\u306eODMR\u3067\u78ba\u8a8d\u3002\u5ba4\u6e29\u52d5\u4f5c\u3092\u5b9f\u8a3c\u3057\u305f\u7d50\u679c\u3067\u306f\u306a\u3044\u3002<\/td>\n<\/tr>\n<tr>\n<td>\u5b54\u306b\u5165\u3063\u305f\u7269\u8cea\u306e\u691c\u51fa\u30fb\u8b58\u5225<\/td>\n<td>\u5fdc\u7528\u306e\u69cb\u60f3\u3002\u4eca\u56de\u306e\u6e2c\u5b9a\u3060\u3051\u3067\u306f\u3001\u691c\u51fa\u3067\u304d\u308b\u7269\u8cea\u3084\u6fc3\u5ea6\u3001\u8b58\u5225\u7cbe\u5ea6\u306f\u6c7a\u307e\u3089\u306a\u3044\u3002<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>T\u2082\u306f\u3001\u30b9\u30d4\u30f3\u306e\u4f4d\u76f8\u95a2\u4fc2\u3092\u4fdd\u3066\u308b\u6642\u9593\u306e\u76ee\u5b89\u3067\u3059\u300250 K\u3067\u306e\u6e2c\u5b9a\u3067\u306f\u3001\u52b1\u8d77\u30ec\u30fc\u30b6\u30fc\u306e\u30d1\u30eb\u30b9\u30a8\u30cd\u30eb\u30ae\u30fc\u30923.2 mJ\u304b\u30890.32 mJ\u3078\u4e0b\u3052\u308b\u3068\u3001T\u2082\u304c\u7d040.78\u30de\u30a4\u30af\u30ed\u79d2\u304b\u3089\u7d044.77\u30de\u30a4\u30af\u30ed\u79d2\u3078\u5ef6\u3073\u307e\u3057\u305f\u3002\u5206\u5b50\u3092\u5f37\u304f\u52b1\u8d77\u3057\u3059\u304e\u308b\u3068\u3001\u52b1\u8d77\u72b6\u614b\u540c\u58eb\u306e\u76f8\u4e92\u4f5c\u7528\u304c\u7121\u8996\u3067\u304d\u306a\u304f\u306a\u308b\u3068\u3044\u3046\u898b\u65b9\u3068\u6574\u5408\u3057\u307e\u3059\u3002\u6700\u3082\u9577\u3044\u5024\u3060\u3051\u3067\u306a\u304f\u3001\u305d\u306e\u5024\u3092\u5f97\u308b\u305f\u3081\u306e\u52b1\u8d77\u6761\u4ef6\u3082\u5408\u308f\u305b\u3066\u8aad\u3080\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002<\/p>\n<h2>\u5206\u5b50\u3092\u53d7\u3051\u5165\u308c\u308b\u5834\u6240\u3068\u3001\u8aad\u307f\u51fa\u3059\u5834\u6240\u3092\u8fd1\u3065\u3051\u308b<\/h2>\n<p>\u3053\u306e\u6750\u6599\u304c\u8208\u5473\u6df1\u3044\u306e\u306f\u3001\u6e2c\u308a\u305f\u3044\u5206\u5b50\u304c\u5165\u308b\u5b54\u306e\u8fd1\u304f\u306b\u3001\u5149\u3067\u8abf\u3079\u3089\u308c\u308b\u30b9\u30d4\u30f3\u3092\u7f6e\u3051\u308b\u3053\u3068\u3067\u3059\u3002\u5c06\u6765\u3001\u5b54\u306b\u5165\u3063\u305f\u5206\u5b50\u304c\u30b9\u30d4\u30f3\u3084\u767a\u5149\u306b\u3069\u3046\u5f71\u97ff\u3059\u308b\u304b\u3092\u6574\u7406\u3067\u304d\u308c\u3070\u3001\u305d\u306e\u5909\u5316\u3092\u7269\u8cea\u691c\u51fa\u306e\u624b\u639b\u304b\u308a\u306b\u3067\u304d\u308b\u304b\u3082\u3057\u308c\u307e\u305b\u3093\u3002\u9aa8\u7d44\u307f\u3084\u6709\u6a5f\u5206\u5b50\u3092\u5909\u3048\u3066\u8a2d\u8a08\u3092\u6bd4\u3079\u3089\u308c\u308b\u3053\u3068\u3082\u3001MOF\u3092\u4f7f\u3046\u5229\u70b9\u3067\u3059\u3002<\/p>\n<p>\u4e00\u65b9\u3001\u5b9f\u969b\u306e\u5206\u6790\u88c5\u7f6e\u3078\u9032\u3080\u306b\u306f\u3001\u5bfe\u8c61\u7269\u8cea\u3092\u5165\u308c\u305f\u3068\u304d\u306e\u5fdc\u7b54\u3001\u307b\u304b\u306e\u7269\u8cea\u3068\u306e\u898b\u5206\u3051\u65b9\u3001\u6e29\u5ea6\u3084\u5149\u306e\u5f37\u3055\u306b\u3088\u308b\u5909\u52d5\u3092\u8abf\u3079\u308b\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002\u8fd1\u8d64\u5916\u306e\u5149\u3092\u4f7f\u3063\u305f\u3068\u3044\u3046\u3060\u3051\u3067\u3001\u4f53\u5185\u3067\u4f7f\u3048\u308b\u30bb\u30f3\u30b5\u30fc\u306b\u306a\u3063\u305f\u308f\u3051\u3067\u3082\u3042\u308a\u307e\u305b\u3093\u3002<\/p>\n<p>\u4eca\u56de\u306e\u6210\u679c\u306f\u3001\u591a\u5b54\u6027\u306e\u7d50\u6676\u306b\u30b9\u30d4\u30f3\u3092\u914d\u7f6e\u3059\u308b\u6750\u6599\u8a2d\u8a08\u3068\u3001\u305d\u306e\u30b9\u30d4\u30f3\u3092\u5149\u3067\u8aad\u3080\u5b9f\u9a13\u304c\u3064\u306a\u304c\u3063\u305f\u70b9\u306b\u3042\u308a\u307e\u3059\u3002\u6b21\u306b\u898b\u308b\u3079\u304d\u306a\u306e\u306f\u3001\u5b54\u306e\u4e2d\u306e\u74b0\u5883\u3092\u5909\u3048\u305f\u3068\u304d\u306b\u3001\u8aad\u307f\u53d6\u308c\u308b\u4fe1\u53f7\u304c\u3069\u3053\u307e\u3067\u5177\u4f53\u7684\u306a\u60c5\u5831\u306b\u306a\u308b\u304b\u3067\u3059\u3002<\/p>\n<p>\u5171\u540c\u7814\u7a76\u306b\u53c2\u52a0\u3057\u305f\u65e5\u672c\u96fb\u5b50\u306e\u4e8b\u696d\u306f\u3001Cyclewave\u306e<a href=\"https:\/\/cyclewave.net\/?p=359\">\u65e5\u672c\u96fb\u5b50\u306e\u4f01\u696d\u89e3\u8aac<\/a>\u3067\u7d39\u4ecb\u3057\u3066\u3044\u307e\u3059\u3002\u96fb\u5b50\u9855\u5fae\u93e1\u306a\u3069\u306e\u5206\u6790\u88c5\u7f6e\u304b\u3089\u534a\u5c0e\u4f53\u306e\u88fd\u9020\u88c5\u7f6e\u307e\u3067\u3001\u7814\u7a76\u3092\u652f\u3048\u308b\u4f1a\u793e\u306e\u5168\u4f53\u50cf\u3092\u77e5\u308b\u305f\u3081\u306e\u6848\u5185\u3067\u3059\u3002<\/p>\n<h2>\u51fa\u5178<\/h2>\n<ul>\n<li>\u6771\u4eac\u5927\u5b66\u5927\u5b66\u9662\u7406\u5b66\u7cfb\u7814\u7a76\u79d1\u300c<a href=\"https:\/\/www.s.u-tokyo.ac.jp\/ja\/press\/11244\/\">\u591a\u5b54\u6027\u91d1\u5c5e\u932f\u4f53 (MOF) \u4e2d\u306e\u96fb\u5b50\u30b9\u30d4\u30f3\u306e\u5149\u691c\u51fa\u3092\u521d\u3081\u3066\u5b9f\u8a3c<\/a>\u300d\uff082026\u5e7410\u67089\u65e5\u767a\u8868\uff09\u3002<\/li>\n<li>Inoue et al., <a href=\"https:\/\/doi.org\/10.1021\/jacs.6c12867\">Optically Addressable Spins in a Metal\u2013Organic Framework<\/a>, Journal of the American Chemical Society 148, 44541\u201344548\uff082026\u5e7410\u67089\u65e5\u516c\u958b\uff09\u3002<a href=\"https:\/\/eprints.gla.ac.uk\/394288\/\">\u30b0\u30e9\u30b9\u30b4\u30fc\u5927\u5b66\u306e\u516c\u958b\u7248\u30fb\u66f8\u8a8c\u60c5\u5831<\/a>\u3002<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"<p>\u5c0f\u3055\u306a\u5206\u5b50\u304c\u5165\u308c\u308b\u5b54\u3092\u6301\u3064\u6750\u6599\u304b\u3089\u3001\u96fb\u5b50\u30b9\u30d4\u30f3\u306e\u72b6\u614b\u3092\u5149\u3067\u8aad\u307f\u53d6\u308b\u3002\u305d\u306e\u4e8c\u3064\u3092\u4e00\u3064\u306e\u7d50\u6676\u3067\u4e21\u7acb\u3067\u304d\u308c\u3070\u3001\u5916\u304b\u3089\u8fd1\u3065\u304f\u5206\u5b50\u3068\u3001\u91cf\u5b50\u72b6\u614b\u306e\u5909\u5316\u3092\u6e2c\u308b\u4ed5\u7d44\u307f\u3068\u3092\u7d50\u3073\u4ed8\u3051\u3089\u308c\u307e\u3059\u3002 \u6771\u4eac\u5927\u5b66\u3001\u65e5\u672c\u96fb\u5b50\u3001\u30b0\u30e9\u30b9\u30b4\u30fc\u5927\u5b66\u306a\u3069\u306e\u5171\u540c\u7814 [&hellip;]<\/p>\n","protected":false},"author":3,"featured_media":1964,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":true,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_feature_clip_id":0,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":false,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2},"jetpack_post_was_ever_published":false},"categories":[34],"tags":[383],"class_list":["post-1965","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-materials-manufacturing","tag-odmr"],"jetpack_publicize_connections":[],"jetpack_sharing_enabled":true,"jetpack_featured_media_url":"https:\/\/quantumsea.net\/wp-content\/uploads\/2026\/10\/qs-mof-triplet-odmr-20261031-3caed4a51ae1.png","_links":{"self":[{"href":"https:\/\/quantumsea.net\/index.php?rest_route=\/wp\/v2\/posts\/1965","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/quantumsea.net\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/quantumsea.net\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/quantumsea.net\/index.php?rest_route=\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/quantumsea.net\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1965"}],"version-history":[{"count":3,"href":"https:\/\/quantumsea.net\/index.php?rest_route=\/wp\/v2\/posts\/1965\/revisions"}],"predecessor-version":[{"id":2107,"href":"https:\/\/quantumsea.net\/index.php?rest_route=\/wp\/v2\/posts\/1965\/revisions\/2107"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/quantumsea.net\/index.php?rest_route=\/wp\/v2\/media\/1964"}],"wp:attachment":[{"href":"https:\/\/quantumsea.net\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1965"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/quantumsea.net\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=1965"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/quantumsea.net\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=1965"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}